Sunday, January 26, 2020

Novel Eu3+-doped Garnet-tpye Tellurate Red-emitting Phosphor

Novel Eu3+-doped Garnet-tpye Tellurate Red-emitting Phosphor A novel Eu3+-doped garnet-tpye tellurate red-emitting phosphor with high thermal stability and color purity Introduction The garnet-related family Li3Ln3Te2O12(Ln=Y, Pr, Nd, Sm-Lu) have been extensively studied as promising solid electrolytes for application in solid state rechargeable lithium-ion batteries for the last few decades [1-4]. In 2006, OCallaghan et al. developed garnet-type Li3Ln3Te2O12 (Ln = Y, Pr, Nd, Sm-Lu) to investigate the relationship between Li site occupation and Li ion conductivity [1]. The lattice constant increases with increasing Ln ionic radius in Li3Ln3Te2O12. These Li3Ln3Te2O12 garnets have exhibited a fairly low ionic conductivity of ∠¼10−5 S cm−1 at 600  °C with a high activation energy (>1 eV) [3]. In 2014, the crystal structures and conductivity data for the most of perspective Li-ion solid electrolytes based on garnet-type metal oxides have been recently reviewed by Thangadurai et al. [4]. Garnet host lattices are of considerable interest due to their wide applications as laser hosts and as phosphors for white light emitting diodes [5]. For example, trivalent rare earth doped Y3Al5O12 (YAG) is one of the widely used systems of compounds for solid state lighting applications. Meanwhile, some new garnet-type compound can be constructed based on the garnet structural model, such as the green-emitting Ca3Sc2Si3O12:Ce3+, the orange-emitting Lu2CaMg2(Si, Ge)3O12:Ce3+, and the green-emitting Ca2LaZr2Ga3O12:Ce3+phosphors [6]. Therefore, the development of phosphors based on garnet-type materials is of great interest. As an important activator, the europium ion is one of the most studied lanthanide activators because of its singular luminescence properties, exhibiting pure red emission transitions with a series of sharp lines arising from the excited state 5D0 to the lower energy state 7F0-6. Eu3+ ions exhibit pure magnetic and electric dipole transitions which make it a very s ensitive probe for the rare earth ion site structure/symmetry. 5D0→7F2 electric dipole (ED) transitions around 610 nm are highly hypersensitive, which is highly sensitive to the symmetry of the Eu3+ sites in the lattices; however, the magnetic dipole transitions (5D0→7F1) are not affected by the environment, and their emission intensities are often used as an internal standard [7]. However, luminescence properties of Eu3+-doped garnet-type Li3Gd3Te2O12 have not been studied yet. In this work, red emitting phosphors Li3Gd3(1-x)Eu3xTe2O12(x = 0.01-0.30) were synthesized by the conventional solid-state reaction. The structure, composition and photoluminescence properties of Li3Gd3Te2O12:Eu3+ phosphors were investigated. In addition, the luminescence quenching of Eu3+ doping concentration and CIE on the photoluminescence spectra were demonstrated in detail. 2. Experimental Procedure    The synthesis of Li3Gd3Te2O12 phosphors doped with Eu3+ ions was carried out via a high-temperature solid-state reaction method. Li2CO3 (99.99%), Gd2O3 (99.99%), TeO2 (99.9%), and Eu2O3 (99.99%) as raw materials, they were purchased from Sigma-Aldrich without further purification and thoroughly mixed in an agate mortar. The mixtures were sintered in air at 900 °C for 10 h. when the reaction was end at 900 °C, the products were cooled down to room temperature without cooling devices. Finally, white powers were obtained by grinding. The relevant reaction formulas are as follows: 3Li2CO3+3(1-x)Gd2O3 + 4TeO2 + 3xEu2O3 + 2O2 = 2Li3Gd3(1-x)Eu3xTe2O12+ 3CO2 The crystal structure of phosphors were characterized for phase formation by using powder X-ray diffraction (XRD) analysis with a Philips XPert MPD (Philips, Netherlands) with Cu KÃŽ ± radiation (ÃŽ » = 1.5418 Ã…). The diffraction patterns were scanned within angular range of 10-70ËÅ ¡(2ÃŽ ¸). The morphology and size of the phosphors were measured using a scanning electron microscope (SEM, JEOL JSM-6490). The photoluminescence (PL) and photoluminescence excitation (PLE) spectra of the samples were analyzed using a Hitachi F-4600 spectrophotometer at room temperature. The temperature-dependent PL spectra of the phosphor were recorded in air on an Edinburgh FLS 920 spectrometer equipped with a 450 W Xe lamp. Results and discussion Li3Gd3Te2O12 belongs to the cubic crystal system, space group of Iad (No.230), in the structure of Li3Gd3Te2O12, Gd3+ and Te6+ cations occupy the 8- and 6-fold sites, and Li+ ions are located exclusively in the tetrahedral (24d) sites, respectively. As shown in Fig. 1, this structure can be considered to be formed from two interpenetrating, body-centered lattices composed of edge-shared distorted [GdO8] cubes [8, 9]. One of these frameworks composed of Gd (black sphere) and O (red sphere) is shown in Fig.1(b) along with selected polyhedra to illustrate the linkages between the [GdO8] units. Tellurium in the [TeO6] polyhedra is accommodated in an octahedral site that shares edges with an edge-linked [GdO8] dimer.   Fig. 2 shows the observed, calculated, and patterns of the Li3Gd2.55Te2O12:0.15Eu3+phosphors, confirmed from Rietveld analysis using GSAS software. The final refinement converged with weighted profile of χ2 = 1.086, Rp = 24.4à ¯Ã‚ ¼Ã¢â‚¬ ¦, and Rwp = 33.9à ¯Ã‚ ¼Ã¢â‚¬ ¦ for Li3Gd2.55Te2O12:0.15Eu3+. It is clear that all the diffraction peaks of these samples are in good agreement with the pure Li3Gd3Te2O12 (JCPDS 22-0683) and no second phase can be found, indicating that each sample is purity phase and that the substitution of Gd3+ by Eu3+ do not significantly influence the crystal structure. Li3Gd3Te2O12 belongs to the cubic system, and the lattice parameters are calculated to be a = b = c = 12.41 Ã…, V = 1911.24 Ã…3, which are consistent with the literature [1]. As the similarity of valence and the ionic radii of Eu3+(r = 0.95 Ã…, CN = 8) is the closest to that of Gd3+(r = 0.94 Ã…, CN = 8), the doped Eu3+ is supposed to substitute for the Gd3+ sites [10].   SEM analysis was carried out to investigate the surface morphology and particle sizes of the synthesized phosphor powder. Fig. 3 shows the representative SEM images of two different concentrations of Li3Gd3Te2O12:xEu3+(a, x = 0.05; b, x = 0.20). It seemed as if these small spherical particles combined together to form big crystallites. The size of particles is found to be in micrometer dimension. Meanwhile, the result indicated that doping content of Eu3+ content in Li3Gd3Te2O12:xEu3+from 0.05 to 0.20 mol did not alter the particle size and agglomeration. The grain size of phosphors is important for their applications in commercial WLEDs. In general, for practical bepowdering applications, the phosphors with micron particles can feed well the commercial demand for WLEDs. Therefore, a long ball-milling step is required to break up the agglomerations and improve the quality of the phosphor powder. Figure 4 shows the excitation spectra of Li3Gd2.55Te2O12:0.15Eu3+ monitored at 613 nm emission (5D0→7F2) at room temperature. The broad band of 200-300 nm (No.1) centered at around 275 nm is called as charge transfer (CT) band which is ascribed to the charge-transfer state (CTS) transition of O2−→Eu3+ ions. The position of this band mightily relies on the host lattice. A sequence of sharp excitation bands(Nos.2-11)between 300 and 500 nm was attributable to the intra-configurational 4f-4f transitions of Eu3+ in the matrix, namely,7F0 to 5FJ, 5H6, 5H3, 5D4, 5L8, 5G3, 5G2, 5L6, 5D3, and 5D2at wavelengths300, 314, 321, 364, 368, 381, 386, 396, 419 and 466 nm respectively [11]. The strongest absorption band located at approximately 396 nm occurred from the 7F0→5L6 transition of Eu3+ ions. A suitable red-emitting ultraviolet light-emitting diode (UV-LED) phosphor should exhibit an absorption of around 400 nm (LED excitation wavelength). Obviously, the Li3Gd3Te2O1 2:Eu3+phosphor has a potential value for white lighting device. Upon 396 nm excitation, the PL emission spectrum of the Li3Gd3Te2O12:Eu3+phosphors was measured as presented in Fig. 5. Clearly, the PL emission spectrum was dominated by a strong red emission with a center of about 613 nm due to the 5D0 →7F2 transition. Meanwhile, there also existed some relatively weak excitation peaks at 570, 596, 655 and 709 nm which are attributed to the 4f-4f transitions of Eu3+ ions from the excited state of 5D0 to 7F0, 7F1, 7F3 and 7F4, respectively. Generally, the local symmetry of Eu3+ site in the crystal lattice can be mostly reflected by Eu3+ emission profile. When Eu3+ ion occupies a crystallographic site with inversion symmetry, its magnetic-dipole 5D0→7F1 orange emission is dominant, while the electric dipole 5D0 →7F2 red emission dominates when possessing the non-centrosymmetrical site [12]. Thus, the I0-2/I0-1 emission ratio can be used in lanthanide-based systems as a probe for the local surroundings of a cation. As shown in Fig . 5, in comparison with that of the 5D0→7F1transition, the emission intensity of the 5D0→7F2 transition was much stronger, and the I0-2/I0-1 ratio was about 4.84. They demonstrated that the Eu3+ ions occupied the low symmetry sites with non-inversion centers in Li3Gd3Te2O12 host lattice. This ratio value is larger in comparison with those of the other Eu3+-doped phosphors. This larger ratio is favorable to improve the red color purity. The intensity of luminescence in phosphors is usually affected by the variation in concentration of activators. Dependence of PL emission intensity of Li3Gd3Te2O12:Eu3+ phosphors on dopant concentration can be seen in Fig. 6. None of wavelength shift or peak was observed for a new site at high Eu3+ concentrations. The emission intensity of the phosphor initially increases up to 15 mol%. The maximum intensity is observed at 15 mol% and after this it starts decreasing. The decrease in the emission intensity is due to concentration quenching effect. The concentration quenching of luminescence is observed when the energy transfer from one activator to another. Blasse has pointed out that if the activator is introduced solely on Z ion sites, xc is the critical concentration, N is the number of Z ions in the unit cell and V is the volume of the unit cell, then there is on the average one activator ion per V/xcN [13]. The critical transfer distance (Rc) is approximately equal to twice the radius of a sphere with this volume: The critical transfer distance of the centerEu3+ in Li3Gd3Te2O12:Eu3+ phosphor by taking the appropriate values of V, N, and xc (1911.24 Ã…3, 8, and 0.15, respectively) is 14 Ã…. The intensity of multipolar interaction can be determined from the change in the emission intensity. The emission intensity is related to the emitting level which has the multipolar interaction. The emission intensity (I) per activator ion is given by the formula [14]: where χ is the activator concentration; Q is a constant of multipolar interaction and equals 3, 6, 8, or 10 for the nearest-neighbor ions, dipole-dipole, dipole-quadrupole or quadrupole-quadrupole interaction, respectively; and K and ÃŽ ² are constants under the same excitation condition for the given host crystal [14, 15]. Then we use this equation to fit the experimental results of the relationship between integrated emission intensity and Eu3+ concentration. The curve of lgI/x vs. lgx in Li3Gd3Te2O12: Eu3+ phosphor based on Fig. 6 is shown in Fig. 7. The figure clearly shows that the relation between lgI/x and lgx is approximately linear and the slope is about -1.0. The Q value calculated based on the linear fitting using Eq. (2) is 3.0. This finding indicates that the concentration quenching of the Eu3+-site emission centers is caused by the energy transfer around the nearest-neighbor ions in the Li3Gd3Te2O12:Eu3+ phosphor. The similar phenomenon has been reported in the Sr1. 7Zn0.3CeO4: Eu3+ phosphor [16]. Both the maintenance of the chromaticity and brightness of white light output are favored by a lower-temperature quenching in the solid-state lighting application. Figure 8 represents the temperature-dependent PL spectra of Li3Gd3Te2O12: Eu3+ excited at 396 nm from 300 K to 460 K. The PL intensity almost unchanged with increase of temperature from 300 K to 460 K. The temperature dependence of the integrated emission intensities normalized at the 300 K value. The sample remained at about 82% of the intensity measured at room temperature, even the sample was heated to 420 K (the temperature at which LEDs typically operate). The thermal quenching temperature T50, the temperature at the 50% emission intensity, was above 500 K for Li3Gd3Te2O12:Eu3+. The Eu3+-activated Li3Ba2Gd3(MoO4)8 red phosphor shows lower quenching temperature and only remain 60% of the room temperature emission intensity at 200  °C. The good thermal quenching performance is similar with K2Ba5Si12O30:Eu2+, BaTiF6:Mn 4+, Sr3Lu0.2(PO4)3:0.8Eu3+phosphor [18-20]. Furthermore, the emission wavelengths showed no shift with increasing temperature. The small decrease in the emission intensity and good color purity stability at higher temperature indicates that the phosphor Li3Gd3Te2O12:Eu3+ has good thermal stability and can serve a potential red emitting phosphor for white LEDs. In order to clarify the thermal quenching behavior and to calculate the activation energy, the Arrhenius equation is fitted to the thermal quenching data of Li3Gd3Te2O12:Eu3+ [21]: Where I0 means the initial intensity at room temperature, I(T) means the intensity at   temperature T, c is a constant, k is Boltzmanns constant (8.62 10−5eV/K), and Eais the activation energy for the thermal quenching process fitted with the thermal quenching data. The inset in Figure 9 plots ln[(I0/I)−1] versus 1/T for Li3Gd3Te2O12:Eu3+. Linear regression showed that the thermal activation energy Ea for quenching was calculated to be ~ 0.22 eV. The thermal quenching of the emission intensity of Eu3+-activated phosphors was due to the excited electrons easily jumping into the CTS band after absorbing thermal energy at high temperatures, which the probability of non-radiative transition may increase. Thus, the emission intensity of Eu3+-activated phosphors decreased with increased temperature [22, 23].    The emission spectra of Li3Gd3Te2O12:0.15Eu3+ and commercial Y2O3:Eu3+ excited at 396 nm were then compared in Fig. 10. Remarkably, the integral emission intensity of Li3Gd3Te2O12:0.15Eu3+ was 3.03 times than that of Y2O3:Eu3+. The CIE chromaticity coordinates of the phosphors were calculated to be (0.642, 0.332) for Li3Gd3Te2O12:0.15Eu3+ according to its PL spectra, which are shown in the CIE 1931 chromaticity diagram in the insets of Fig. 10. It was found that the CIE coordinates of the present red phosphor are more close to those of the NTSC standard CIE chromaticity coordinate values for red (0.67, 0.33) standard value, which is better than those of the commercial red phosphors Y2O3:Eu3+ (0.49, 0.32) [24] and Y2O2S:Eu3+ (0.65, 0.36) [25]. Furthermore, to better understand the red emission of the Eu3+-activated Li3Gd3Te2O12 phosphors, the color purity was calculated according to the following expression described by Fred Schubert [26]: where (x, y) denotes the CIE coordinate of the synthesized compounds, (xi, yi) presents the color coordinate of the white illumination and the (xd, yd) is the color coordinates of the dominant wavelength. The dominant wavelength point can be calculated from the intersection of the connecting line between the equal energy point and the sample point. The color purity of Li3Gd3Te2O12:0.15Eu3+ (0.642, 0.332) phosphors is determined to be around 92.6%. This indicates high color purity and excellent chromaticity coordinate characteristics. The inset image in Fig. 10 shows that strong red emission was observed with the naked eyes when Li3Gd3Te2O12:0.15Eu3+is under a 365 nm UV lamp. Conclusion A novel garnet-type red-emitting phosphor Li3Gd3Te2O12:Eu3+ was prepared by the convenient solid-state reaction. The excitation and emission spectra and the dependence of luminescence on temperature were studied. The excitation spectra indicate that this phosphor can be effectively excited by near-UV light, which matches the emission wavelength of near-UV-LED chips well. The phosphor shows intense red emission, which has a high quenching temperature and can keep a stable color purity with elevated temperature. The optimum dopant concentration of Eu3+ ions in Li3Gd3Te2O12:Eu3+ was around 15 mol%, and the critical transfer distance of Eu3+ was calculated to be 14 Ã…. The concentration quenching is probably caused by the energy transfer among the nearest-neighbor ions in the Li3Gd3Te2O12:Eu3+ phosphor. Because of its good excitation profile and stable luminescence properties at high temperature, Eu3+-doped Li3Gd3Te2O12 phosphors are a potential red phosphors for NUV chip-based WLEDs and display devices.

Saturday, January 18, 2020

Constructivism and the Syrian Civil War Essay

Constructivism is a normative international relations theory that seeks to understand the importance of society’s actions and extrapolate its meaning (Adler, 1997, pp. 319-320). According to constructivism, any actor can have xan agency in international relations such as states, institutions and individuals and is dissimilar to realism and liberalism where instead of the assumption that states are self-interested and rational, it accepts that these actor’s interests and rationality are socially constructed and are constitutive of and by its identity (Bozdaglioglu, 2007, pp. 122-123). The formation of the state’s interests is inborn in its identity, whereas realism shapes them for survival of the state, and liberalism states they are derived from cooperation and interdependence. Interests are not innate or intrinsic (Risse-Kappen, 1995, p. 502). As it is socially ‘constructed’, a state can then be deconstructed and changed when all interests, identities and assumptions have been recognised. These interests, such as law, rules, norms and institutions are ingrained in the system of international relations and are fundamental for instating change. Constructivism is the best theory for understanding the events in Syria because it shows how social identities and an actors’ interests and preferences are socially constructed and can instigate conflict. Due to the multiple groups motivated in this conflict multiple social identities are present which are incompatible. Ultimately, the Syrian Civil War is an identity conflict with each identity consisting of their own beliefs that each find exclusive. As identities and interests are constitutive, the interests of a group serve as a propellant for social action (Bozdaglioglu, 2007, pp. 131-132). Therefore these constructed interests motivate the social identities of the groups and need to be redefined in order for trust to be established. A social identity can be defined as a socially constructed set of meanings that one attributes to oneself (Bozdaglioglu, 2007, p. 132). It is created predominately through the political choices and the actor’s interactions, assumptions, interpretation and collective meanings and serves a core role in the Syrian conflict (Adler, 1997, p. 324). The presence of multiple different social identities with numerous beliefs in the Syrian conflict is incompatible and result in societal ‘friction’. Al-Assad’s regime does not represent the general public, in the  sense that it favours the Shia minority and suppresses all other identities (Vallely, 2014). This is a conflict of cultural identity where all groups hold different interests in which each find exclusive. Constructivism is the only theory in which acknowledges this identity crisis between the parties involved in the Syrian civil war. Trust and peace need to be fortified and in order to do so a common identity needs to be worked towards and founded by all reasonable parties. As President Barack Obama states in relation to Syria: â€Å"Peace can be achieved by allowing opposing parties to freely express and discuss their respective opinions which would ideally result in peaceful resolutions based on views held in common by these parties† (Obama, 2 013) To do so, the structure of norms in which develops behaviour and interests must be deconstructed and changed (Checkel, 1998, p. 328). An actor’s behaviour is complex to understand as identities are not fixed and known, and therefore it cannot be deduced from the character that is assumed a state represents (Palan, 2004, p. 14). Looking through a constructivist lens, norms are collective understandings that motivate actors and therefore effect the identity and interest (Checkel, 1998, pp. 327-328). A dominant conflict in which sparked and fuels the Syrian civil war is that of the sectarian tension between the Sunni and Shia branches of Islam (Hinnebusch, 2008, pp. 263-265). Deeply embedded in the Syrian civil war is that of a religious uproar between sects (Vallely, 2014). The uprising in Syria consists of sectarian religious overtones in which resulted in a domestic clash between Shia and Sunni sects. With a government predominately Shia and 75% of the population Sunni (United States Central Intelligence Agency, 2014) a domestic clash between Shia government and Sunni population must be resolved in order for a common identity of the state to be formed and trust established. The al-Assad regime’s Shia representation clashes with the general Sunni public and in order for this struggle to be resolved, an impartial and independent government identity must be formed. Constructivism is the only theory in which recognises these relations and its authoritative role in the civil war. It shows how the Sunni-Shia relations are an important sector of the social structure of Syria in which the actions of actors with certain identities and interests are possible (Wendt, 1995). Constructivism distinguishes two core assumptions of realism and liberalism in which allow for a more advanced understanding of the social structure of  Syria. Firstly, that institutions and structures only inhibit behaviour of states with fixed interests and secondly, that the identity of a state is perceived only through physical capabilities (Checkel, 1998). Relaxing these assumptions allows social structures to become important and allows the formation of identities and interests t o be defined by more than just behavioural constraints (Checkel, 1998). This is exemplified by the role religious institutions have in the Syria. As the Shia minority came into power, the protests become stronger and the demonstrations from the Sunni population are seen by the al-Assad regime as terroristic. This lead to a redefining of the parties’ identities, conclusively leading to each side identifying the other as terrorists or criminal gangs. The identity and interests of the state are therefore constitutive of and by the other parties and not only through physical capabilities. Social structures such as norms and culture, have a profound effect on agents, being characteristic of each parties’ identities and therefore interests (Checkel, 1998). In conclusion, constructivism is the best theory to explain what is happening in Syria. By analysing the central determinants of state behaviour, identity and interests, the current dissatisfaction of the status quo can be deconstructed and changed to form one common identity. Only social interaction and meaningful dialogue can guide the agents in identifying interests that is shared by the general public. Only when one common identity is defined, will trust and peace, as well as domestic, social and legal norms be established. Bibliography Adler, E. (1997). Seizing the Middle Ground: Constructivism in World Politics. European Journal of Internation Relations, 3(3), 319 – 363. Bozdaglioglu, Y. (2007). Constructivism and Identity Formation: An Interactive Approach. Uluslararasi Hukuk ve Politika, 3(11), 121-144. Checkel, J. T. (1998). The Constructivist Turn in International Relations Theory. World Politics, 50, 324-348. Hinnebusch, R. (2008). Modern Syria Politics. History Compass, 6(1), 263-285. Obama, B. (2013). U.N General Assembly Speech. United Nations. New York: United Nations General Assembly. Palan, R. (2004). Constructivism and Globalisation: From Units to Encounters in International Affairs. Cambridge Review of International Affairs, 17(1), 11-23. Risse-Kappen, T. (1995). Democratic Peace – Warlike Democracies? A Social Constructivist Interpretation of the Liberal Argument. Eurpoean Journal of International Relations, 1(4), 491-517. United States Central Intelligence Agency. (2014, April 2). The World Factbook: Syria. Retrieved from Central Intelligence Agency: https://www.cia.gov/library/publications/the-world-factbook/geos/sy.html Vallely, P. (2014, February 19). The vicious schism between Sunni and Shia has been poisoning Islam for 1,400 years – and it’s getting worse . The Independent . Wendt, A. (1992). Anarchy is what states make of it: the social construction of power politics. International Organisation, 46(2), 391-425. Wendt, A. (1995). Constructing International Politics. International Security, 20(1), 71-81.

Friday, January 10, 2020

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Wednesday, January 1, 2020

Yum The Worlds Largest Fast Food Company - 1229 Words

YUM operates over 39,000 fast food locations under their 3 main brands: KFC, Pizza Hut, and Taco Bell. YUM has grown to be the world’s largest fast food company, based on the number of operating locations (Interfax, 2013). YUM maintains a competitive brand by strategically looking for opportunities outside of the US. YUM has continued to grow globally, with over 50% of its income coming from outside of the US (Company, n.d.). In 2015, YUM opened 2,365 new restaurants around the world and this year they expect to better that number slightly. This equates to roughly 6 new stores daily. They have utilized franchise locations to fuel continued growth, while minimizing a portion of the overall risk. YUM has experienced tremendous success in China with KFC and Pizza Hut. In 2015, YUM decided to spin off their Chinese division and create YUM China. The move is intended to allow the individual management teams to focus on their respective businesses, which operate in separate areas of the industry life cycle. YUM has not only expanded into China, but India, Africa, and Russia as well. YUM’s aggressive plan to exploit new potential markets as the US fast food industry is in a mature phase of its life cycle has paid off well for the company. That does not mean that YUM does not recognize the importance of strong brand recognition in the US. YUM has worked to evolve their menus to meet the US consumers changing habits. The Taco Bell brand has been focused on reinventing itself in theShow MoreRelatedYum Brands Essay696 Words   |  3 PagesDescribe Pizza Hut and KFCs investment strategy in Latin America. Latin America was appealing to Yum brands because of its close proximity to the United States, language and cultural similarities, and the North America free Trade Agreement eliminated tariffs on goods traded between the United States. 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It isRead MoreCompetitor And Financial Analysis : Burger King Essay964 Words   |  4 Pagesfoodservice companies† (Burger King Worldwide 4) like McDonalds possesses. â€Å"McDonald’s and Wendy’s are Burger King’s primary competitors† (Burger King Worldwide). Wendy’s has various opportunities that give it some advantageous or external growth, but threats from â€Å"intense competition may erode the group’s market share† (The Wendy’s Company 4). Wendy’s is a very prominent corporation in the marketplace of North America. â€Å"The group is the world’s third largest quick-service restaurant company in the hamburgerRead MorePizza Hut : The Largest Pizza Chain1576 Words   |  7 PagesExecutive Summary Pizza Hut is the largest pizza chain in the world, with over 13,000 units in more than 94 countries. Pizza Hut Canada has over 300 units from coast to coast, with two distinct restaurant builds to service dine-in and delivery channels. 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The Mcdonald’s stock symbol or stock ticker is MCD and this company trades in the New York Stock Exchange. The McDonald s headquarters complex, McDonald s Plaza, is located in Oak Brook, Illinois. The business began in 1940, with a restaurant opened by brothers Richard and Maurice McDonald in San Bernardino, California. The present corporation dates its foundin g to the opening of a franchised restaurant by businessman RayRead MorePopeyes vs Kentucky Fried Chicken1731 Words   |  7 PagesKuyee Slanger Principles of Management Instructor: Ms. Livingston 03/29/2012 Midterm Popeyes Fried Chicken Vs Kentucky Fried Chicken Popeyes: To be the world’s best quick service restaurant. Being the best means providing outstanding quality service, cleanliness, and value, so that makes every customer in every restaurant smile. SWOT Analysis: Strengths: The strength of Popeyes is based on its distinctive brand and style of Louisiana spicy chickens that it provides on its menu along withRead MoreFinancial Analysis - Yum! Brands and Darden Restaurant2097 Words   |  9 PagesYum! Brands Yum! Brands started out as Tricon Global Restaurants in 1997 as the result of a separation from PepsiCo, and became owners of the KFC, Pizza Hut and Taco Bell brand names worldwide. Yum! Brands is now a Fortune 500 company based out of Louisville, Kentucky and the world’s largest restaurant company in the world in terms of system restaurants. With over 37,000 restaurants in over 110 countries, Yum! Brands dominates four sectors of the quick-service food industry: Mexican with the TacoRead MoreThe Success Of Yum, Pizza Hut, And Taco Bell3306 Words   |  14 PagesIntroduction Yum! Brands is an American fast food corporation, which a fortune of 500 corporation. Yum operates the other three parts of brand: KFC, Pizza Hut, and Taco Bell. It located in Louisville, Kentucky, and it is the largest fast food enterprise in the system units of about 41,000 restaurants around the world. The gross profit in 2014 of Yum! Brands are more than $15 billion. As Yum! Brands play an important role in global markets, and it also has positively market improvement in China. ThisRead MoreKentucky Fried Chicken and Global Fast Food Industry2025 Words   |  9 PagesKENTUCKY FRIED CHICKEN AND THE GLOBAL FAST-FOOD INDUSTRY UNIVERSITY OF DHAKA A report submitted to the Faculty of Business Studies in partial fulfillment of the requirements of the final term examination in Principle of Management, Summer-2013. Submitted To: Prof. Dr. Shahid Uddin Ahmed Course Instructor EM 502 (S-B) Principle of Management Submitted By: Group B Sahin Sultana, Roll-66 Kanis Fatima, Roll-76 Nowshin Ahmed, Roll-63 Tabassum Mohsin Chowdhury